Geochemistry and sediment in the main stream of the Ca River basin,Vietnam: weathering process,solute-discharge relationships,and reservoir impact

Acta Geochimica - In this study, we investigated the chemical composition of dissolved solids in the Ca River basin, North-Central Vietnam. Water samples were collected from August 2017 to July...     

软弱泥质砂岩地层中输水隧洞稳定性研究

泥质砂岩属于黏土岩,具有典型的遇水软化特征。在泥质砂岩富水地层中进行隧道开挖是地下工程的一个挑战性问题。研究了围岩软化与未软化条件下泥质砂岩地层中输水隧洞的稳定性和支护时间。首先,介绍了泥质砂岩遇水软化的力学试验结果;然后,采用基于Hoek-Brown强度准则的岩体参数评价方法,评估泥质砂岩在围岩软化与未软化条件下的力学参数;再后,以兰州水源地引水隧洞为依托工程,采用数值模拟方法对泥质砂岩隧洞软化与未软化工况的围岩稳定性进行了计算分析,得出泥质砂岩遇水软化对隧洞安全性存在显著影响;最后,采用位移收敛法,研究了泥质砂岩软化与未软化工况中,保障隧洞施工安全的合理支护时机。研究表明,泥质砂岩未软化工况中,可考虑隧道围岩初期支护在距掌子面4～5 m位置实施;而在泥质砂岩遇水软化工况中,初期支护建议在掌子面开挖后立刻支护。研究成果可为泥质砂岩地层隧洞的安全施工提供依据。     

A field study investigating the potential use of phosphorus combined with organic amendments on cadmium accumulation by wheat and subsequent rice

A field study was performed to determine the efficiency of diammonium phosphate (DAP) applied alone or combined with biochar, lignite, and farmyard manure (FYM) on growth and cadmium (Cd) accumulation in wheat and rice. Before crop sowing, different treatments were applied in the field such as a control (T₁), DAP alone (0.1%, T₂), DAP + lignite (0.05% each, T₃), DAP + FYM (0.05% each, T₄), and DAP + biochar (0.05% each, T₅). Afterwards, the wheat seeds were sown in the soil. At wheat postharvest, rice was sown without any further treatment. Raw effluent was applied as an irrigation source during the whole growth period of both crops since it is the common practice of the farmers of study area. It was revealed that the use of amendments enhanced the yield and photosynthesis but lowered the Cd contents in straw as well as grains of both crops. In both crops, the highest yield of straw and grain was found in DAP + FYM whereas the lowest Cd concentration was found in DAP alone. The ammonium bicarbonate-DTPA extractable Cd of post wheat and post rice soils were decreased while the soil pH and immobilization index were increased in all treatments as compared with the control. The present field study highlighted that the DAP + FYM can be effective in increasing yield with decreased Cd concentrations in crop grains.     

Characterization of carbon monoxide,methane and nonmethane hydrocarbons in emerging cities of Saudi Arabia and Pakistan and in Singapore

We investigate the composition of 63 C₂-C₁₀ nonmethane hydrocarbons (NMHCs), methane (CH₄) and carbon monoxide (CO), in Jeddah, Mecca, and Madina (Saudi Arabia), in Lahore, (Pakistan), and in Singapore. We established a database with which to compare and contrast NMHCs in regions where ambient levels and emissions are poorly characterized, but where conditions are favorable to the formation of tropospheric ozone, and where measurements are essential for improving emission inventories and modeling. This dataset will also serve as a base for further analysis of air pollution in Western Saudi Arabia including, but not limited to, the estimation of urban emissions and long range pollution transport from these regions. The measured species showed enhanced levels in all Saudi Arabian cities compared to the local background but were generally much lower than in Lahore. In Madina, vehicle exhaust was the dominant NMHC source, as indicated by enhanced levels of combustion products and by the good correlation between NMHCs and CO, while in Jeddah and Mecca a combination of sources needs to be considered. Very high NMHC levels were measured in Lahore, and elevated levels of CH₄ in Lahore were attributed to natural gas. When we compared our results with 2010 emissions from the MACCity global inventory, we found discrepancies in the relative contribution of NMHCs between the measurements and the inventory. In all cities, alkenes (especially ethene and propene) dominated the hydroxyl radical (OH) reactivity (k _OH) because of their great abundance and their relatively fast reaction rates with OH.     

Assessment of Metals Concentration and Ecotoxicology of the Sediment Core of Rehri Creek, Karachi Coast, Pakistan

Trace metal concentrations were investigated in a recent sediment core collected from the Rehri Creek area of the Karachi coast,Sindh-Pakistan.The core was sliced horizontally at 2.5-cm intervals to determine grain size,sediment composition,pH,organic matter,and acid-leachable trace metals:cadmium,chromium,copper,lead,and zinc.The trace metals were analyzed by ICP.To separate anthropogenic from geogenic input,several approaches were made,including comparison with sediment quality guidelines—ecotoxicological sense of heavy metal contamination and classification by quantitative indexes.Grain-size analysis and sediment composition of core sample show a sandy nature with neutral pH.Elemental sequence(ES)of the trace metals is in the order of Zn(19.2-109.56 ppm)>Si(66.46-101.71 ppm)>Ba(12.05-26.86 ppm)>As(8.18-17.36 ppm)>Ni(4.2-14.69 ppm)>Cr(3.02-9.62 ppm)>Pb(2.79-6.83 ppm)>Cu(2.2-5.29 ppm)>Co(0.9-2.05 ppm).Thus it is likely that the area may face a serious threat of metal pollution with the present deposition rates unless stringent pollution control norms are adopted.The Sediment Geo-accumulation Index shows that there is no Cr,Cu,Ni,Pb,Zn,or Fe pollution;however,the former index and the Pollution Load Index indicate arsenic pollution in the sediments.     

The P3 kimberlite and P4 lamproite,Wajrakarur kimberlite field,India: mineralogy,and major and minor element compositions of olivines as records of their phenocrystic vs xenocrystic origin

Distinctly different groundmass mineralogy characterise the hypabyssal facies, Mesoproterozoic diamondiferous P3 and P4 intrusions from the Wajrakarur Kimberlite Field, southern India. P3 is an archetypal kimberlite with macrocrysts of olivine and phlogopite set in a groundmass dominated by phlogopite and monticellite with subordinate amounts of serpentine, spinel, perovskite, apatite, calcite and rare baddeleyite. P4 contains mega- and macrocrysts of olivine set in a groundmass dominated by clinopyroxene and phlogopite with subordinate amounts of serpentine, spinel, perovskite, apatite, and occasional gittinsite, and is mineralogically interpreted as an olivine lamproite. Three distinct populations of olivine, phlogopite and clinopyroxene are recognized based on their microtextural and compositional characteristics. The first population includes glimmerite and phlogopite–clinopyroxene nodules, and Mg-rich olivine macrocrysts (Fo 90–93) which are interpreted to be derived from disaggregated mantle xenoliths. The second population comprises macrocrysts of phlogopite and Fe-rich olivine (Fo 81–89) from P3, megacrysts and macrocrysts of Fe-rich olivine (Fo 85–87) from P4 and a rare olivine–clinopyroxene nodule from P4 which are suggested to have a genetic link with the precursor melt of the respective intrusions. The third population represents clearly magmatic minerals such as euhedral phenocrysts of Fe-rich olivine (Fo 85–90) crystallised at mantle depths, and olivine overgrowth rims formed contemporaneously with groundmass minerals at crustal levels. Close spatial association and contemporaneous emplacement of P3 kimberlite and P4 lamproite is explained by a unifying petrogenetic model which involves the interaction of a silica-poor carbonatite melt with differently metasomatised wall rocks in the lithospheric mantle. It is proposed that the metasomatised wall rock for lamproite contained abundant MARID-type and phlogopite-rich metasomatic veins, while that for kimberlite was relatively refractory in nature.

     

A quantitative assessment of changes in seasonal potential predictability for the twentieth century

Changes over the twentieth century in seasonal mean potential predictability (PP) of global precipitation, 200 hPa height and land surface temperature are examined by using 100-member ensemble. The ensemble simulations have been conducted by using an intermediate complexity atmospheric general circulation model of the International Center for Theoretical Physics, Italy. Using the Hadley Centre sea surface temperature (SST) dataset on a 1° grid, two 31 year periods of 1920–1950 and 1970–2000 are separated to distinguish the periods of low and high SST variability, respectively. The standard deviation values averaged for the (“Niño-3.4”; 5°S–5°N, 170°W–120°W) region are 0.71 and 1.15 °C, for the periods of low and high SST variability, respectively, with a percentage change of 62 % during December–January–February (DJF). The leading eigenvector and the associated principal component time series, also indicate that the amplitude of SST variations have positive trend since 1920s to recent years, particularly over the El Niño Southern Oscillation (ENSO) region. Our hypothesis states that the increase in SST variability has increased the PP for precipitation, 200 hPa height and land surface temperature during the DJF. The analysis of signal and noise shows that the signal-to-noise (S/N) ratio is much increased over most of the globe, particularly over the tropics and subtropics for DJF precipitation. This occurs because of a larger increase in the signal and at the same time a reduction in the noise, over most of the tropical areas. For 200 hPa height, the S/N ratio over the Pacific North American (PNA) region is increasing more than that for the other extratropical regions, because of a larger percentage increase in the signal and only a small increase in noise. It is also found that the increase in seasonal mean transient signal over the PNA region is 50 %, while increase in the noise is only 12 %, during the high SST variability period, which indicates that the increase in signal is more than the noise. For DJF land surface temperature, the perfect model notion is utilized to confirm the changes in PP during the low and high SST variability periods. The correlation between the perfect model and the other members clearly reveal that the seasonal mean PP changed. In particular, the PP for the 31 years period of 1970–2000 is higher than that for the 31 years period of 1920–1950. The land surface temperature PP is increased in northern and southern Africa, central Europe, southern South America, eastern United States and over Canada. The increase of the signal and hence the seasonal mean PP is coincides with an increase in tropical Pacific SST variability, particularly in the ENSO region.